Amazing Spider-Man #13 – First Appearance of Mysterio

Amazing Spider-Man Annual #1 (1964) - First appearance of the Sinister Six

Amazing Spider-Man #24

Amazing Spider-Man Annual #4

Amazing Spider-Man #66
Amazing Spider-Man #67

Amazing Spider-Man #141
Amazing Spider-Man #142

Amazing Spider-Man #193
Amazing Spider-Man #194 - First appearance of Black Cat
Amazing Spider-Man #195
Amazing Spider-Man #196
Amazing Spider-Man #197
Amazing Spider-Man #198
Amazing Spider-Man #199
Amazing Spider-Man #200

Peter Parker, The Spectacular Spider-Man #50
Peter Parker, The Spectacular Spider-Man #51

Amazing Spider-Man #334
Amazing Spider-Man #335
Amazing Spider-Man #336
Amazing Spider-Man #337
Amazing Spider-Man #338
Amazing Spider-Man #339

Spider-Man #18
Spider-Man #19
Spider-Man #20
Spider-Man #21
Spider-Man #22
Spider-Man #23

Webspinners: Tales of Spider-Man #1 (1999)
Webspinners: Tales of Spider-Man #2
Webspinners: Tales of Spider-Man #3

Daredevil Vol. 2 #1 (1998)
Daredevil Vol. 2 #2
Daredevil Vol. 2 #3
Daredevil Vol. 2 #4
Daredevil Vol. 2 #5
Daredevil Vol. 2 #6
Daredevil Vol. 2 #7
Daredevil Vol. 2 #8

Friendly Neighborhood Spider-Man #11
Friendly Neighborhood Spider-Man #12
Friendly Neighborhood Spider-Man #13

Web of Spider-Man Vol. 2 #4

Amazing Spider-Man #618
Amazing Spider-Man #619
Amazing Spider-Man #620

Amazing Spider-Man #659
Amazing Spider-Man #660

Amazing Spider-Man #680
Amazing Spider-Man #681
Amazing Spider-Man #682
Amazing Spider-Man #683
Amazing Spider-Man #684
Amazing Spider-Man #685

Amazing Spider-Man: Ends of the Earth #1 (2012)

Amazing Spider-Man #686
Amazing Spider-Man #687

Spider-Men #1 (2012)
Spider-Men #2
Spider-Men #3
Spider-Men #4
Spider-Men #5

Spider-Man/Deadpool #1 (2016)
Spider-Man/Deadpool #2
Spider-Man/Deadpool #3
Spider-Man/Deadpool #4
Spider-Man/Deadpool #5

Read Dead No More: The Clone Conspiracy here.

Ben Reilly: Scarlet Spider #18
Ben Reilly: Scarlet Spider #19

Dead Man Logan #1 (2019)
Dead Man Logan #2
Dead Man Logan #3
Dead Man Logan #4
Dead Man Logan #5

Symbiote Spider-Man #1 (2019)
Symbiote Spider-Man #2
Symbiote Spider-Man #3
Symbiote Spider-Man #4
Symbiote Spider-Man #5

Amazing Mary Jane #1 (2019)
Amazing Mary Jane #2
Amazing Mary Jane #3
Amazing Mary Jane #4
Amazing Mary Jane #5

Amazing Spider-Man Vol. 5 #70

Sinister War #1 (2021)

Amazing Spider-Man Vol. 5 #71

Sinister War #2
Sinister War #3

Amazing Spider-Man Vol. 5 #72

Sinister War #4

Amazing Spider-Man Vol. 5 #73

Amazing Spider-Man Vol. 6 #45
Amazing Spider-Man Vol. 6 #46
Amazing Spider-Man Vol. 6 #47
Amazing Spider-Man Vol. 6 #48

All-New Spider-Gwen: The Ghost-Spider #7
All-New Spider-Gwen: The Ghost-Spider #8
All-New Spider-Gwen: The Ghost-Spider #9
All-New Spider-Gwen: The Ghost-Spider #10