Mysterio

Quentin Beck does not possess superhuman abilities but he is an expert designer of special effects devices and stage illusions,  a master hypnotist and magician,  and an amateur chemist.  He had extensive knowledge of hand-to-hand combat techniques learned as a stuntman,  allowing him to engage in combat with Spider-Man despite his foe’s superior physical abilities.

First Appearance:  Amazing Spider-Man #13 (1964)
Creators:  Stan Lee,  Steve Ditko
Powers:  Master Hypnotist,  Inventor

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Issues

Black entries are ongoing series
Green entries are Limited series
Red entries are One-Shots
Orange are alternate universe stories
Blue is for comments

Reading Order

Amazing Spider-Man #13 – First Appearance of Mysterio

Amazing Spider-Man Annual #1 (1964) – First appearance of the Sinister Six

Amazing Spider-Man #24

Amazing Spider-Man Annual #4

Amazing Spider-Man #66
Amazing Spider-Man #67

Amazing Spider-Man #141
Amazing Spider-Man #142

Amazing Spider-Man #193
Amazing Spider-Man #194 – First appearance of Black Cat
Amazing Spider-Man #195
Amazing Spider-Man #196
Amazing Spider-Man #197
Amazing Spider-Man #198
Amazing Spider-Man #199
Amazing Spider-Man #200

Peter Parker, The Spectacular Spider-Man #50
Peter Parker, The Spectacular Spider-Man #51

Webspinners: Tales of Spider-Man #1 (1999)
Webspinners: Tales of Spider-Man #2
Webspinners: Tales of Spider-Man #3

Daredevil Vol. 2 #1 (1998)
Daredevil Vol. 2 #2
Daredevil Vol. 2 #3
Daredevil Vol. 2 #4
Daredevil Vol. 2 #5
Daredevil Vol. 2 #6
Daredevil Vol. 2 #7
Daredevil Vol. 2 #8

Friendly Neighborhood Spider-Man #11
Friendly Neighborhood Spider-Man #12
Friendly Neighborhood Spider-Man #13

Web of Spider-Man Vol. 2 #4

Amazing Spider-Man #618
Amazing Spider-Man #619
Amazing Spider-Man #620