Black Widow

Natasha Romanova was originally a Russian spy, an enemy of Iron Man.  Eventually she defected to the United States,  becoming an agent of  S.H.I.E.L.D.,  and a member of the Avengers.

First Appearance:  Tales of Suspense #52 (1964)
Creators:  Stan Lee,  Don Heck
Powers:  Superhuman Agility & Reflexes,  Peak Human Strength & Speed,  Expert Marksman,  Martial Artist,  and Tactician

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Issues

Black entries are ongoing series
Green entries are Limited series
Red entries are One-Shots
Orange are alternate universe stories
Blue is for comments

Reading Order

Daredevil #187
Daredevil #188
Daredevil #189
Daredevil #190

Black Widow: Web of Intrigue #1 (1999)

Uncanny X-Men #268

Captain America #372
Captain America #373
Captain America #374
Captain America #375
Captain America #376
Captain America #377
Captain America #378

Black Widow #1 (1999)
Black Widow #2
Black Widow #3

Black Widow: Breakdown #1 (2001)
Black Widow: Breakdown #2
Black Widow: Breakdown #3

Black Widow: Pale Little Spider #1 (2002)
Black Widow: Pale Little Spider #2
Black Widow: Pale Little Spider #3

Daredevil Vol. 2 #61
Daredevil Vol. 2 #62
Daredevil Vol. 2 #63
Daredevil Vol. 2 #64

Black Widow Vol. 2 #1 (2004)
Black Widow Vol. 2 #2
Black Widow Vol. 2 #3
Black Widow Vol. 2 #4
Black Widow Vol. 2 #5
Black Widow Vol. 2 #6

Captain America Vol. 5 #27
Captain America Vol. 5 #28
Captain America Vol. 5 #29
Captain America Vol. 5 #30
Captain America Vol. 5 #31
Captain America Vol. 5 #32
Captain America Vol. 5 #33
Captain America Vol. 5 #34
Captain America Vol. 5 #35
Captain America Vol. 5 #36
Captain America Vol. 5 #37
Captain America Vol. 5 #38
Captain America Vol. 5 #39
Captain America Vol. 5 #40
Captain America Vol. 5 #41
Captain America Vol. 5 #42
Captain America Vol. 5 #43
Captain America Vol. 5 #44
Captain America Vol. 5 #45
Captain America Vol. 5 #46
Captain America Vol. 5 #47
Captain America Vol. 5 #48
Captain America Vol. 5 #49
Captain America Vol. 5 #50

Captain America #600
Captain America #601
Captain America #602
Captain America #603
Captain America #604
Captain America #605

Black Widow: Deadly Origin #1 (2010)
Black Widow: Deadly Origin #2
Black Widow: Deadly Origin #3
Black Widow: Deadly Origin #4

Captain America #606
Captain America #607
Captain America #608
Captain America #609
Captain America #610

Black Widow Vol. 4 #1 (2010)
Black Widow Vol. 4 #2
Black Widow Vol. 4 #3
Black Widow Vol. 4 #4
Black Widow Vol. 4 #5

Captain America #611
Captain America #612
Captain America #613
Captain America #614
Captain America #615
Captain America #616
Captain America #617
Captain America #618
Captain America #619

Black Widow Vol. 4 #6
Black Widow Vol. 4 #7
Black Widow Vol. 4 #8

Secret Avengers #16
Secret Avengers #17
Secret Avengers #18
Secret Avengers #19
Secret Avengers #20
Secret Avengers #21

Amazing Spider-Man #682
Amazing Spider-Man #683
Amazing Spider-Man #684
Amazing Spider-Man #685
Amazing Spider-Man #686
Amazing Spider-Man #687

Winter Soldier #1 (2012)
Winter Soldier #2
Winter Soldier #3
Winter Soldier #4
Winter Soldier #5
Winter Soldier #6
Winter Soldier #7
Winter Soldier #8
Winter Soldier #9
Winter Soldier #10
Winter Soldier #11
Winter Soldier #12
Winter Soldier #13
Winter Soldier #14

Secret Avengers Vol. 2 #1 (2013)
Secret Avengers Vol. 2 #2
Secret Avengers Vol. 2 #3
Secret Avengers Vol. 2 #4
Secret Avengers Vol. 2 #5
Secret Avengers Vol. 2 #6
Secret Avengers Vol. 2 #7
Secret Avengers Vol. 2 #8
Secret Avengers Vol. 2 #9
Secret Avengers Vol. 2 #10
Secret Avengers Vol. 2 #11
Secret Avengers Vol. 2 #12
Secret Avengers Vol. 2 #13
Secret Avengers Vol. 2 #14
Secret Avengers Vol. 2 #15
Secret Avengers Vol. 2 #16

Secret Avengers Vol. 3 #1 (2014)
Secret Avengers Vol. 3 #2
Secret Avengers Vol. 3 #3
Secret Avengers Vol. 3 #4

Black Widow Vol. 5 #1 (2013)
Black Widow Vol. 5 #2
Black Widow Vol. 5 #3
Black Widow Vol. 5 #4
Black Widow Vol. 5 #5
Black Widow Vol. 5 #6
Black Widow Vol. 5 #7
Black Widow Vol. 5 #8
Black Widow Vol. 5 #9
Black Widow Vol. 5 #10
Black Widow Vol. 5 #11
Black Widow Vol. 5 #12
Black Widow Vol. 5 #13
Black Widow Vol. 5 #14
Black Widow Vol. 5 #15
Black Widow Vol. 5 #16
Black Widow Vol. 5 #17
Black Widow Vol. 5 #18
Black Widow Vol. 5 #19
Black Widow Vol. 5 #20

Secret Avengers Vol. 3 #5 (2014)
Secret Avengers Vol. 3 #6
Secret Avengers Vol. 3 #7
Secret Avengers Vol. 3 #8
Secret Avengers Vol. 3 #9
Secret Avengers Vol. 3 #10
Secret Avengers Vol. 3 #11
Secret Avengers Vol. 3 #12
Secret Avengers Vol. 3 #13
Secret Avengers Vol. 3 #14
Secret Avengers Vol. 3 #15